SkyDrive is now OneDrive, and SkyDrive Pro is now OneDrive for Business. Read more about this change at From SkyDrive to OneDrive
If you have the OneDrive for Business sync app, you can sync team site libraries to your computer, and then work with your library files directly in your file system. This also gives you access to the library documents when you’re not online. This video shows you how to sync a team site library and how to find the synced library folder in your File Explorer.